Albert V Gysegem

42619157, Apr 14, 1981

Feb 19, 1980

6/122198

Gabriel H. Law - Whittier CA
Albert P. Gysegem - Monrovia CA

Ameron, Inc. - Monterey Park CA

C07F 722

2604297

Compositions for protecting materials from growth of pestiferous organisms, and particularly for protecting marine surfaces from fouling organisms, are formed from precursors having the formula ##STR1## where m is from 1 to about 10, where each X is independently selected from the group consisting of alkyl and alkoxyalkyl radicals containing less than about 6 carbon atoms and Y, where Y has the formula ##STR2## where R. sub. 1, R. sub. 2 and R. sub. 3 are independently selected from the group consisting of alkyl, cycloalkyl, and aryl radicals, where R. sub. 1, R. sub. 2 and R. sub. 3 contain in combination up to about 18 carbon atoms. The ratio of the tin atoms to silicon atoms in the precursors is at least about 1:50. The precursors can be directly used as an additive for coatings. The precursors can also be used by subjecting them to hydrolysis and polycondensation to form an organotin substituted polysiloxane for use as an additive and a binder for coatings.

42985439, Nov 3, 1981

Feb 19, 1980

6/122199

Gabriel H. Law - Whittier CA
Albert P. Gysegem - Monrovia CA

Ameron, Inc. - Monterey Park CA

C07F 722

2604297

Compositions for protecting materials from growth of pestiferous organisms, and particularly for protecting marine surfaces from fouling organisms, are formed from precursors having the formula ##STR1## where m is from 1 to about 10, where each X is independently selected from the group consisting of alkyl and alkoxyalkyl radicals containing less than about 6 carbon atoms and Y, where Y has the formula ##STR2## where R. sub. 1 R. sub. 2 and R. sub. 3 are independently selected from the group consisting of alkyl, cycloalkyl, and aryl radicals, where R. sub. 1, R. sub. 2 and R. sub. 3 contain in combination up to about 18 carbon atoms. The ratio of the tin atoms to silicon atoms in the precursors is at least about 1:50. The precursors can be directly used as an additive for coatings. The precursors can also be used by subjecting them to hydrolysis and polycondensation to form an organotin substituted polysiloxane for use as an additive and a binder for coatings.

40801900, Mar 21, 1978

Aug 26, 1976

5/718149

Gabriel H. Law - Whittier CA
Albert Peter Gysegem - Monrovia CA

Ameron, Inc. - Monterey Park CA

A01N 900
C08G 7704
C07F 722

71 67

Compositions for protecting materials from growth of pestiferous organisms, and particularly for protecting marine surfaces from fouling organisms, are formed from precursors having the formula ##STR1## where m is from 1 to about 10, where each X is independently selected from the group consisting of alkyl and alkoxyalkyl radicals containing less than about 6 carbon atoms and Y, where Y has the formula ##STR2## where R. sub. 1, R. sub. 2 and R. sub. 3 are independently selected from the group consisting of alkyl, cycloalkyl, and aryl radicals, where R. sub. 1, R. sub. 2 and R. sub. 3 contain in combination up to about 18 carbon atoms. The ratio of the tin atoms to silicon atoms in the precursors is at least about 1:50. The precursors can be directly used as an additive for coatings. The precursors can also be used by subjecting them to hydrolysis and polycondensation to form an organotin substituted polysiloxane for use as an additive and a binder for coatings.

RE309095, Apr 20, 1982

Feb 15, 1980

6/121725

Gabriel H. Law - Whittier CA
Albert P. Gysegem - Monrovia CA

Ameron, Inc. - Monterey Park CA

A01N 900
C07F 722
C08G 7704

71 67

Compositions for protecting materials from growth of pestiferous organisms, and particularly for protecting marine surfaces from fouling organisms, are formed from precursors having the formula ##STR1## where m is from 1 to about 10, where each X is independently selected from the group consisting of alkyl and alkoxyalkyl radicals containing less than about 6 carbon atoms and Y, where Y has the formula ##STR2## where R. sub. 1, R. sub. 2 and R. sub. 3 are independently selected from the group consisting of alkyl, cycloalkyl, and aryl radicals, where R. sub. 1, R. sub. 2 and R. sub. 3 contain in combination up to about 18 carbon atoms. The ratio of the tin atoms to silicon atoms in the precursors is at least about 1:50. The precursors can be directly used as an additive for coatings. The precursors can also be used by subjecting them to hydrolysis and polycondensation to form an organotin substituted polysiloxane for use as an additive and a binder for coatings.

42279291, Oct 14, 1980

Dec 8, 1977

5/858708

Gabriel H. Law - Whittier CA
Albert P. Gysegem - Monrovia CA

Ameron, Inc. - Monterey Park CA

C09D 514
C09D 538

106 117

Compositions for protecting materials from growth of postiferous organisms, and particularly for protecting marine surfaces from fouling organisms, are formed from precursors having the formula ##STR1## where m is from 1 to about 10, where each X is independently selected from the group consisting of alkyl and alkoxyalkyl radicals containing less than about 6 carbon atoms and Y, where Y has the formula ##STR2## where R. sub. 1, R. sub. 2 and R. sub. 3 are independently selected from the group consisting of alkyl, cycloalkyl, and aryl radicals, where R. sub. 1, R. sub. 2 and R. sub. 3 contain in combination up to about 18 carbon atoms. The ratio of the tin atoms to silicon atoms in the precursors is at least about 1:50. The precursors can be directly used as an additive for coatings. The precursors can also be used by subjecting them to hydrolysis and polycondensation to form an organotin substituted polysiloxane for use as an additive and a binder for coatings.

41136659, Sep 12, 1978

Feb 3, 1977

5/765223

Gabriel H. Law - Rancho Palos Verdes CA
Albert Peter Gysegem - Monrovia CA

Ameron, Inc. - Monterey Park CA

C08G 7700

260 37SB

Chemically resistant coatings comprise a binder, the major portion of which is prepared by reacting, in the presence of an acidic solution, trialkoxysilanes with aliphatic polyols and/or silicone intermediates. The silanes have the formula ##STR1## where R. sub. 1 is selected from the group consisting of alkyl, aryl and cycloalkyl groups containing up to about 6 carbon atoms and each R. sub. 2 is independently selected from the group consisting of alkyl, hydroxyalkyl, alkoxyalkyl and hydroxyalkoxyalkyl groups containing up to about 6 carbon atoms. The aliphatic polyols contain an average of at least two carbon bonded hydroxyl groups per polyol. The silicone intermediates have the formula ##STR2## WHERE EACH R. sub. 3 is selected from the group consisting of the hydroxy group and alkyl, aryl, and alkoxy groups having up to about 6 carbon atoms. Each R. sub. 4 is selected from the group consisting of hydrogen and alkyl and aryl groups having up to about 6 carbon atoms.

42500745, Feb 10, 1981

Sep 6, 1979

6/072897

Raymond E. Foscante - Yorba Linda CA
Albert P. Gysegem - Monrovia CA
Pamela J. Martinich - Long Beach CA
Gabriel H. Law - Rancho Palos Verdes CA

Ameron, Inc. - Monterey Park CA

C08G 7726
C08L 6300
C08L 8306

260 328EP

Polymeric structures having interpenetrating matrices in cured form comprising an epoxy-polyamine network and a polysiloxane network. The interpenetrating network physical and chemical properties are improved over those of either polymeric component alone. The network can be prepared by simultaneously reacting epoxy resin having at least two oxirane groups with amine curing agent, and having present at least 0. 1 equivalent of silane, water being substantially uniformly distributed throughout the mixture in an amount sufficient to bring about substantial hydrolytic polycondensation of the silane to form a cross-linked interpenetrating polymer network. The amine curing agent may be substituted wholly or in part by aminosilane. Sources of silane may include aminosilane and epoxysilane. Relative reaction rates of formation of the polymeric networks are controlled, to get good intertwining of the two polymers.

42295637, Oct 21, 1980

Aug 3, 1979

6/063190

Raymond E. Foscante - Yorba Linda CA
Albert P. Gysegem - Monrovia CA
Pamela J. Martinich - Long Beach CA

Ameron, Inc. - Monterey Park CA

C08G 5944

528 99

Epoxy resins are cured with an amine adduct of orthohydroxybenzoic acid of the formula: ##STR1## where x is from 2 to about 8.