Mohamed H Eddaoudi

6893564, May 17, 2005

May 30, 2002

10/157182

Ulrich Mueller - Neustadt, DE
Lisa Lobree - Mannheim, DE
Michael Hesse - Worms, DE
Omar Yaghi - Ann Arbor MI, US
Mohamed Eddaoudi - Ann Arbor MI, US

BASF Aktiengesellschaft - Ludwigshafen
The Regents of the University of Michigan - Ann Arbor MI

B01D039/00
C07F009/00

2105021, 210503, 2105101, 502151, 502152, 502153, 502154, 540465, 554225, 264239

The present invention relates to a novel class of shaped bodies containing metal-organic frameworks. Said metal-organic frameworks comprise at least one metal ion and at least one at least bidentate organic compound and contain at least one type of micro- and mesopores or micro- or mesopores. Said shaped bodies comprise at least one metal-organic framework material and may optionally contain further substances, in particular at least one supporting material.

6929679, Aug 16, 2005

Feb 1, 2002

10/061147

Ulrich Müller - Neustadt, DE
Klaus Harth - Altleiningen, DE
Markus Hölzle - Kirchheim, DE
Michael Hesse - Worms, DE
Lisa Lobree - Mannheim, DE
Wolfgang Harder - Weinheim, DE
Omar M. Yaghi - Ann Arbor MI, US
Mohamed Eddaoudi - Ann Arbor MI, US

BASF Aktiengesellschaft - Ludwigshafen
The Regents of the University of Michigan - Ann Arbor MI

H01M008/04
F17C011/00
B01D053/02

95 90, 96108, 206 07, 429 34, 502526

The present invention relates to the technical field of storing gas including methane and hydrogen, in particular to the fuel cell technology. In particulars it relates to a method of using a metallo-organic framework material comprising pores and at least one metal ion and at least one at least bidentate organic compound.

6930193, Aug 16, 2005

Apr 30, 2002

10/137043

Omar M. Yaghi - Ann Arbor MI, US
Mohamed Eddaoudi - Ann Arbor MI, US
Hailian Li - Ann Arbor MI, US
Jaheon Kim - Ann Arbor MI, US
Nathaniel Rosi - Ann Arbor MI, US

The Regents of the University of Michigan - Ann Arbor MI

C07F013/00
C07F015/00
C07F011/00

556 46, 556 43, 556 51, 556 58, 556 72, 556 89, 556112, 556113, 556136, 556141, 534 15

An isoreticular metal-organic framework (IRMOF) and method for systematically forming the same. The method comprises the steps of dissolving at least one source of metal cations and at least one organic linking compound in a solvent to form a solution; and crystallizing the solution under predetermined conditions to form a predetermined IRMOF. At least one of functionality, dimension, pore size and free volume of the IRMOF is substantially determined by the organic linking compound.

7196210, Mar 27, 2007

May 2, 2005

11/119563

Omar M. Yaghi - Ann Arbor MI, US
Mohamed Eddaoudi - Ann Arbor MI, US
Hailian Li - Ann Arbor MI, US
Jaheon Kim - Ann Arbor MI, US
Nathaniel Rosi - Ann Arbor MI, US

The Regents of the University of Michigan - Ann Arbor MI

C07F 13/00
C07F 15/00
C07F 11/00

556 46, 556 43, 556 51, 556 58, 556 72, 556 89, 556112, 556113, 556136, 556141, 534 15

The ability to design and construct solid-state materials with pre-determined structures is a grand challenge in chemistry. An inventive strategy based on reticulating metal ions and organic carboxylate links into extended networks has been advanced to a point that has allowed the design of porous structures in which pore size and functionality can be varied systematically. MOF-5, a prototype of a new class of porous materials and one that is constructed from octahedral Zn—O—C clusters and benzene links, was used to demonstrate that its 3-D porous system can be functionalized with the organic groups, —Br, —NH2, —OCH, —OCH, —HC, and —HC, and its pore size expanded with the long molecular struts biphenyl, tetrahydropyrene, pyrene, and terphenyl. The ability to direct the formation of the octahedral clusters in the presence of a desired carboxylate link is an essential feature of this strategy, which resulted in the design of an isoreticular (having the same framework topology) series of sixteen well-defined materials whose crystals have open space representing up to 91. 1% of the crystal volume, and homogeneous periodic pores that can be incrementally varied from 3. 8 to 28.

7279517, Oct 9, 2007

Oct 18, 2002

10/492192

Ulrich Mueller - Neustadt, DE
Michael Stoesser - Neuhofen, DE
Raimund Ruppel - Dresden, DE
Eva Baum - Schwarzheide, DE
Edward Bohres - Mannheim, DE
Marcus Sigl - Mannheim, DE
Lisa Lobree - Philadelphia PA, US
Omar M. Yaghi - Ann Arbor MI, US
Mohamed Eddaoudi - Ann Arbor MI, US

BASF Aktiengesellschaft - Ludwigshafen
University of Michigan - Ann Arbor MI

C08L 75/00
C07C 67/26

524199, 560209

The present invention relates to a process for the alkoxylation of organic compounds comprising the reaction of at least one organic compound with at least one alkoxylating agent in the presence of a catalyst system, wherein a polyether alcohol is obtained. The catalyst system comprises a metallo organic framework mate-rial comprising pores and at least one metal ion and at least one at least bidentate organic compound, which is coordinately bounded to said metal ion. Furthermore it relates to polyurethanes or polyurethane foams, which are obtainable by using a prepared polyether alcohol as a starting material.

8034952, Oct 11, 2011

Nov 17, 2008

12/272764

Mohamed Eddaoudi - Tampa FL, US
Farid Nouar - Tampa FL, US
Jarrod F. Eubank - Tampa FL, US
Lukasz Wojtas - Tampa FL, US
Till Bousquet - Tampa FL, US
Michael Zaworotko - Tampa FL, US

University of South Florida - Tampa FL

C07F 15/00
C07F 1/00

548103, 556110

The present invention generally relates to supramolecular assemblies and their modes of synthesis. The supramolecular assemblies include a 1:8 ratio of a supermolecular polyhedral building block and a triangular molecular building block, the supermolecular polyhedral building block having points of extension corresponding to the vertices of a rhombicuboctahedron for linking the supermolecular polyhedral building block to the triangular building block.

8415493, Apr 9, 2013

Apr 24, 2006

11/410359

Mohamed Eddaoudi - Tampa FL, US
Yunling Liu - Tampa FL, US

University of South Florida - Tampa FL

C07F 3/00
B01J 20/22
B32B 3/26

556132, 502401, 4283044

The subject invention pertains to metal organic frameworks (MOF) having zeolite-net-like topology, their methods of use, and their modes of synthesis. The ZMOFs are produced by combining predesigned tetrahedral building, generated in situ using heterochelation, with polyfunctional ligands that have the commensurate angle and the required donor groups for the chelation. Each molecular building block is contrasted of a single metal ion and ligands with both heterochelation functionality and bridging functionality. Advantageously, zeolite-net-like MOFs of the subject invention are porous and contain large functional cavities, which is useful for encapsulating large molecules.

20030078311, Apr 24, 2003

Oct 19, 2001

10/039733

Ulrich Muller - Neustadt, DE
Michael Stober - Neuhofen, DE
Raimund Ruppel - Dresden, DE
Eva Baum - Schwarzheide, DE
Edward Bohres - Ludwigshafen, DE
Marcus Sigl - Mannheim, DE
Lisa Lobree - Mannheim, DE
Omar Yaghi - Ann Arbor MI, US
Mohamed Eddaoudi - Ann Arbor MI, US

C08G018/30
C08G018/38
C08G018/48
C08G018/52
C08G018/00

521/155000, 568/679000, 528/076000

The present invention relates to a process for the alkoxylation of organic compounds comprising the reaction of at least one organic compound with at least one alkoxylating agent in the presence of a catalyst system, wherein a polyetheralcohol is obtained, characterized in that the catalyst system comprises a metallo organic framework material comprising pores and at least one metal ion and at least one at least bidentate organic compound, which is coordinately bounded to said metal ion, and polyurethanes or polyurethane foams, which are obtainable by using a prepared polyether alcohol as a starting material.