US Patent:
20110111300, May 12, 2011
Inventors:
William S. DelHagen - Menlo Park CA, US
Rainer J. Fasching - Mill Valley CA, US
Ghyrn E. Loveness - Menlo Park CA, US
Song Han - Foster City CA, US
Eugene M. Berdichevsky - Menlo Park CA, US
Constantin I. Stefan - San Jose CA, US
Yi Cui - Sanford CA, US
Mark C. Platshon - Menlo Park CA, US
Assignee:
AMPRIUS INC. - Menlo Park CA
International Classification:
H01M 4/134
H01M 4/13
H01M 4/139
B05D 5/12
US Classification:
429223, 429209, 4292181, 427 77, 427 78, 977700
Abstract:
Provided are novel electrodes for use in lithium ion batteries. An electrode includes one or more intermediate layers positioned between a substrate and an electrochemically active material. Intermediate layers may be made from chromium, titanium, tantalum, tungsten, nickel, molybdenum, lithium, as well as other materials and their combinations. An intermediate layer may protect the substrate, help to redistribute catalyst during deposition of the electrochemically active material, improve adhesion between the active material and substrate, and other purposes. In certain embodiments, an active material includes one or more high capacity active materials, such as silicon, tin, and germanium. These materials tend to swell during cycling and may loose mechanical and/or electrical connection to the substrate. A flexible intermediate layer may compensate for swelling and provide a robust adhesion interface. Provided also are novel methods of fabricating electrodes containing one or more intermediate layers.