Inventors:
Robert A. Administrator of the National Aeronautics and Space Frosch
Warren W. Christensen - San Jose CA
Ludwig A. Mayer - San Jose CA
Fritz H. Woeller - Sunnyvale CA
International Classification:
C08J 940
C08J 310
B01D 5320
Abstract:
New chromatographic materials have been developed to serve as the stationary phase of columns used in the separation of atmospheric gases. These materials consist of a crosslinked porous polymer matrix, e. g. , a divinylbenzene polymer, into which has been embedded an inorganic complexed ion such as N,N'-ethylene-bis(acetylacetoniminato)-cobalt (II). Organic nitrogenous bases, such as pyridine, may be incorporated into the chelate polymer complexes to increase their chromatographic utility. With such materials, the process of gas chromatography is greatly simplified, especially in terms of time and quantity of material needed for a gas separation.