Inventors:
William Augustine Wachter - Baton Rouge LA
Gregg Johnston Howsmon - Baton Rouge LA
Jeffrey Thomas Elks - Baton Rouge LA
Leroy Russell Clavenna - Baton Rouge LA
Hyung Suk Woo - Baton Rouge LA
Claude Clarence Culross - Baton Rouge LA
Charles Harrison Mauldin - Baton Rouge LA
Christine Esther Kliewer - Clinton NJ
Assignee:
ExxonMobil Research and Engineering Company - Annandale NJ
International Classification:
C07C 2700
US Classification:
518709, 518715, 518700, 502 20, 502 22, 502 23, 502241, 502325, 502326, 208 15, 208 18, 208 61, 208 33
Abstract:
A process for increasing the hydrogenation activity, particularly the carbon monoxide hydrogenation activity, of a catalyst or catalyst precursor comprised of a particulate solids support component and a catalytic metal, or metals component, preferably cobalt; cobalt alone or cobalt and an additional metal, or metals added to promote or modify the reaction produced by the cobalt. Treatment of the catalyst, or catalyst precursor is conducted at low temperature ranging from ambient to about 275Â C. sufficient to form on the surface of a catalyst precursor, e. g. , a cobalt catalyst precursor, a cobalt metal hydroxide, low valence cobalt metal oxide, or mixture of cobalt metal hydroxide and low valence cobalt metal oxide. Sometimes also metallic metal, e. g. , cobalt, is also formed, and dispersed on the surface of the support.